All Problems

Molecules and Crystals

Problem 6.189

In a chain of identical atoms the vibration frequency ω\omega depends on wave number kk as ω=ωmaxsin(ka/2),\omega=\omega_{\max } \sin (k a / 2), where ωmux\omega_{m u x} is the maximum vibration frequency, k=2π/λk=2 \pi / \lambda is the wave number corresponding to frequency ω,a\omega, a is the distance between neighbouring atoms. Making use of this dispersion relation, find the dependence of the number of longitudinal vibrations per unit frequency interval on ω,\omega, i.e. dN/dω,d N / d \omega, if the length of the chain is l.l . Having obtained dN/dω,d N / d \omega, find the total number NN of possible longitudinal vibrations of the chain.

Reveal Answer
(a) dN/dω=2l/πaωmax2ω2d N / d \omega=2 l / \pi a \sqrt{\omega_{\max }^{2}-\omega^{2}} (b) N=l/a,\quad N=l / a, \quad i.e. is equal to the number of the atoms in the chain.