All Problems

First law of thermodynamics, heat capacity

Problem 2.50

One mole of an ideal gas whose adiabatic exponent equals γ\gamma undergoes a process in which the gas pressure relates to the tem perature as p=aTα,p=a T^{\alpha}, where aa and α\alpha are constants. Find: (a) the work performed by the gas if its temperature gets an increment ΔT\Delta T (b) the molar heat capacity of the gas in this process; at what value of α\alpha will the heat capacity be negative?

Reveal Answer
2.50. (a) A=(1α)RΔTA=(1-\alpha) R \Delta T (b) C=R/(γ1)+R(1α)C=R /(\gamma-1)+R(1-\alpha) C<0C<0 for α>γ/(γ1)\alpha>\gamma /(\gamma-1)