All Problems

Equation of the gas state processes

Problem 2.24

Find the isothermal compressibility xx of a Van der Waals gas as a function of volume VV at temperature TT. Note. By definition, x=1VVpx=-\frac{1}{V} \frac{\partial V}{\partial p}.

Reveal Answer
x=V2(Vb)2/[RTV32a(Vb)2]x=V^{2}(V-b)^{2} /\left[R T V^{3}-2 a(V-b)^{2}\right]