A piece of copper of mass m=90 gm=90 \mathrm{~g}m=90 g at a temperature t1t_{1}t1 =90∘C=90{ }^{\circ} \mathrm{C}=90∘C was placed in a calorimeter in which ice of mass 50 g50 \mathrm{~g}50 g was at a temperature −3∘C.-3{ }^{\circ} \mathrm{C} .−3∘C. Find the entropy increment of the piece of copper by the moment the thermal equilibrium is reached.