All Problems

Liquids. Capillary effects

Problem 2.180

Find the increment of the free energy of the surface layer when two identical mercury droplets, each of diameter \(d=1.5 \mathrm{~mm}\) merge isothermally.

Reveal Answer
ΔF=2παd2(21/31)=1.5μJ\Delta F=2 \pi \alpha d^{2}\left(2^{-1 / 3}-1\right)=-1.5 \mu \mathrm{J}